In the Riskland campaign (Dorastor), there is a SIZ 1 or 2 scorpionman which supports the others with spells, and stabs at PCs' feet with a needle.
I have used in the far past chaotic poisons : acid-squirting stinger, petrifying venom, etc. The idea was that PCs should not be too sure of what's coming out of the sting. Keeps'em on their toes.
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